000 03399cam a2200361Ia 4500
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003 CUTN
005 20130621113831.0
008 080605s2008 njua b 001 0 eng d
010 _a 2008299321
020 _a9812779132
020 _a9789812779137
035 _a(OCoLC)ocn191658618
035 _a(OCoLC)191658618
035 _a(NNC)6862577
040 _aYDXCP
_cYDXCP
_dBAKER
_dBTCTA
_dBWX
_dOCLCQ
_dDLC
_dOrLoB-B
050 0 0 _aQC318.I7
_b.K54 2008
082 0 0 _a536/.7
_222
100 1 _aKjelstrup, Signe.
_zKJE
245 1 0 _aNon-equilibrium thermodynamics of heterogeneous systems /
_cSigne Kjelstrup, Dick Bedeaux.
260 _aHackensack, NJ :
_bWorld Scientific,
_cc2008.
300 _axv, 434 p. :
_bill. ;
_c24 cm.
490 1 _aSeries on advances in statistical mechanics ;
_vv. 16
504 _aIncludes bibliographical references (p. 393-413) and index.
505 0 0 _g1.
_tScope --
_g2.
_tWhy Non-Equilibrium Thermodynamics? --
_g3.
_tThermodynamic Relations for Heterogeneous Systems --
_gPt. A.
_tGeneral Theory --
_g4.
_tThe Entropy Production for a Homogeneous Phase --
_g5.
_tThe Excess Entropy Production for the Surface --
_g6.
_tThe Excess Entropy Production for a Three Phase Contact Line --
_g7.
_tFlux Equations and Onsager Relations --
_g8.
_tTransport of Heat and Mass --
_g9.
_tTransport of Heat and Charge --
_g10.
_tTransport of Mass and Charge --
_gPt. B.
_tApplications --
_g11.
_tEvaporation and Condensation --
_g12.
_tMulti-Component Heat and Mass Diffusion --
_g13.
_tA Nonisothermal Concentration Cell --
_g14.
_tThe Transported Entropy --
_g15.
_tAdiabatic Electrode Reactions --
_g16.
_tThe Liquid Junction Potential --
_g17.
_tThe Formation Cell --
_g18.
_tPower from Regular and Thermal Osmosis --
_g19.
_tModeling the Polymer Electrolyte Fuel Cell --
_g20.
_tMeasuring Membrane Transport Properties --
_g21.
_tThe Impedance of an Electrode Surface --
_g22.
_tNon-Equilibrium Molecular Dynamics Simulations --
_g23.
_tThe Non-Equilibrium Two-Phase van der Waals Model.
520 1 _a"The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems." "The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight."--BOOK JACKET.
650 0 _aNonequilibrium thermodynamics.
700 1 _aBedeaux, Dick.
830 0 _aSeries on advances in statistical mechanics ;
_vv. 16.
900 _bTOC
942 _2ddc
_cBOOKS
948 1 _a20080909
_bc
_cdc21
_dMPS
999 _c6353
_d6353