000 03525cam a2200301 a 4500
001 8842
003 CUTN
005 20130621162809.0
008 100311s2010 enka b 001 0 eng
010 _a 2010010754
020 _a9780470770832 (hardback)
040 _aDLC
_cDLC
_dDLC
042 _apcc
050 0 0 _aQD471
_b.S73 2010
082 0 0 _a541/.224
_222
245 0 0 _aStable radicals :
_bfundamentals and applied aspects of odd-electron compounds /
_ceditor, Robin G. Hicks.
260 _aThe Atrium, Chichester, UK ;
_a[Hoboken, N.J.] :
_bWiley,
_c2010.
300 _axviii, 588 p. :
_bill., (some col.) ;
_c26 cm.
504 _aIncludes bibliographical references and index.
520 _a"Stable radicals- molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques- have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds a team of international experts provide a broad-based overview of stable radicals, from the fundamental aspects of specific classes of stable neutral radicals to their wide range of applications including synthesis, materials science and chemical biology. Topics covered include: triphenylmethyl and related radicals polychlorinated triphenylmethyl radicals: towards multifunctional molecular materials phenalenyls, cyclopentadienyls, and other carbon-centered radicals the nitrogen oxides: persistent radicals and van der Waals complex dimers nitroxide radicals: properties, synthesis and applications the only stable organic sigma radicals: di-tert-alkyliminoxyls. Delocalized radicals containing the hydrazyl [R2N-NR] unit metal-coordinated phenoxyl radicals stable radicals containing the thiazyl unit: synthesis, chemical, and materials properties stable radicals of the heavy p-block elements application of stable radicals as mediators in living-radical polymerization nitroxide-catalyzed alcohol oxidations in organic synthesis metal-nitroxide complexes: synthesis and magneto-structural correlations rechargeable batteries using robust but redox-active organic radicals spin labeling: a modern perspective functional in vivo EPR spectroscopy and imaging using nitroxides and trityl radicals biologically relevant chemistry of nitroxides. Stable Free Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds is an essential guide to this fascinating area of chemistry for researchers and students working in organic and physical chemistry and materials science."--
520 _a"Stable radicals - molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques - have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body"--
650 0 _aRadicals (Chemistry)
_xStability.
650 0 _aElectron mobility.
700 1 _aHicks, Robin G.
_q(Robin Gary),
_d1968-
_zHIC
906 _a7
_bcbc
_corignew
_d1
_eecip
_f20
_gy-gencatlg
942 _2ddc
_cBOOKS
999 _c6585
_d6585