A chemist's guide to density functional theory /

Koch, Wolfram.

A chemist's guide to density functional theory / Wolfram Koch, Max C. Holthausen. - 2nd.ed. - Weinheim ; Chichester : Wiley-VCH, c2000. - xiii, 294 p. ill. ; 24 cm.

Previous ed.: 2000.

Includes bibliographical references and index.

Elementary Quantum Chemistry --
The Schrodinger Equation --

The Variational Principle --


The Hartree-Fock Approximation --


The Restricted and Unrestricted Hartree-Fock Models --




Electron Correlation --





Electron Density and Hole Functions --






The Electron Density --







The Pair Density --








Fermi and Coulomb Holes --







The Fermi Hole --









The Coulomb Hole --









The Electron Density as Basic Variable: Early Attempts --









Does it Make Sense? --











The Thomas-Fermi Model --












Slater's Approximation of Hartree-Fock Exchange --













The Hohenberg-Kohn Theorems --













The First Hohenberg-Kohn Theorem: Proof of Existence --















The Second Hohenberg-Kohn Theorem: Variational Principle --
















The Constrained-Search Approach --

















Do We Know the Ground State Wave Function in Density















Functional Theory? --

















The Kohn-Sham Approach --

















Orbitals and the Non-Interacting Reference System --


















Orbitals and the Non-Interacting Reference System --


















The Kohn-Sham Equations --



















The Kohn-Sham Potential is Local --





















The Exchange-Correlation Energy in the Kohn-Sham and




















Hartree-Fock Schemes --


Do the Kohn-Sham Orbitals Mean Anything? --


Is the Kohn-Sham Approach a Single Determinant Method? --




The Unrestricted Kohn-Sham Formalism --




On Degeneracy, Ensembles and other Oddities --






Excited States and the Multiplet Problem --







The Quest for Approximate Exchange-Correlation Functionals --








Is There a Systematic Strategy? --









The Adiabatic Connection --










From Holes to Functionals --











The Local Density and Local Spin-Density Approximations --












The Generalized Gradient Approximation --













Hybrid Functionals --













Self-Interaction.















3527303723 9783527303724


Density functionals.
Quantum chemistry
Electronic structure.--Mathematics.

541.28 / KOC