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18679cam a22003738i 4500 |
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22351722 |
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CUTN |
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20230622163100.0 |
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211214s2022 flu b 001 0 eng |
| 010 ## - LIBRARY OF CONGRESS CONTROL NUMBER |
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| LC control number |
2021061054 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
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| International Standard Book Number |
9780367768706 |
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(hardback) |
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| International Standard Book Number |
9781032006161 |
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(paperback) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
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9781003174929 |
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(ebook) |
| 040 ## - CATALOGING SOURCE |
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| Original cataloging agency |
DLC |
| Language of cataloging |
eng |
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rda |
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DLC |
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pcc |
| 050 00 - LIBRARY OF CONGRESS CALL NUMBER |
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QD251.3 |
| Item number |
.S654 2022 |
| 082 00 - DEWEY DECIMAL CLASSIFICATION NUMBER |
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| Classification number |
547 |
| Edition number |
23/eng20220412 |
| Item number |
SMI |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
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| Personal name |
Smith, Michael, |
| Dates associated with a name |
1946 October 17- |
| Relator term |
author. |
| 245 10 - TITLE STATEMENT |
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| Title |
Organic chemistry : |
| Remainder of title |
an acid-base approach / |
| Statement of responsibility, etc |
Michael B. Smith. |
| 250 ## - EDITION STATEMENT |
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| Edition statement |
Third edition. |
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FL : |
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CRC Press, |
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c2023. |
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| Projected publication date |
2206 |
| 300 ## - PHYSICAL DESCRIPTION |
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pages cm |
| 504 ## - BIBLIOGRAPHY, ETC. NOTE |
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| Bibliography, etc |
Includes bibliographical references and index. |
| 505 ## - FORMATTED CONTENTS NOTE |
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| Formatted contents note |
Chapter 1: Introduction<br/><br/>1.1. A Brief History of Organic Chemistry<br/><br/>1.2. The Variety and Beauty of Organic Molecules<br/><br/> <br/><br/>Chapter 2: Why Is an Acid-Base Theme Important?<br/><br/>2.1. Traditional Acid and Base Theory<br/><br/>2.2. There are Two Acid-Base Definitions: How Are They Related?<br/><br/>2.3. Acid-Base Equilibria and Equilibrium Constants<br/><br/>2.4. Electronegativity and Atom Size<br/><br/>2.4.A. Electronegativity <br/><br/>2.4. B. Atom Size<br/><br/>2.5. Atom Size and Electronegativity Arguments Applied to Acids and Bases <br/><br/>2.6. Resonance, Electron Dispersion and Base Strength<br/><br/>2.7. Lewis Acids and Bases<br/><br/>2.8. Why Is Acid–Base Chemistry a Theme for Organic Chemistry?<br/><br/>2.9. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 3: Bonding<br/><br/>3.1. Atomic orbitals and Electrons <br/><br/>3.1.A. Atomic Orbitals<br/><br/>3.1.B. Electronic Configuration<br/><br/>3.2. Ionic versus Covalent Chemical Bonds<br/><br/>3.3. Covalent Bonds<br/><br/>3.4. Linear Combination of Atomic Orbital (LCAO) Model<br/><br/>3.5. Tetrahedral Carbons and sp3 Hybridization<br/><br/>3.5.A. The Experimentally Determined Structure of Methane<br/><br/>3.5.B. Electron Promotion and sp3 Hybridization <br/><br/>3.5.C. The Hybrid Carbon Model of sp3-Hybrid Orbitals <br/><br/>3.6. The Valence Shell Electron Pair Repulsion (VSEPR) Model<br/><br/>3.7. Breaking Covalent Bonds<br/><br/>3.8. Carbon Bonded to Heteroatoms<br/><br/>3.8.A. A Covalent Bond Between Carbon and a Heteroatom: Bond Polarization<br/><br/>3.8.B. Bond Polarity, Bond Moments, and Bond Strength<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 4: Alkanes, Isomers, and an Introduction to Nomenclature<br/><br/>4.1. Alkanes <br/><br/>4.2. Structural Variations of Alkane Hydrocarbons<br/><br/>4.2.A. Straight-chain and Branched Alkanes<br/><br/>4.2.B. Isomers<br/><br/>4.3. The IUPAC Rules of Nomenclature<br/><br/>4.3.A. Prefixes and Simple Alkanes<br/><br/>4.3.B. Common Names<br/><br/>4.3.C. Halogens are Substituents<br/><br/>4.3.D. Multiple Substituents<br/><br/>4.3.E. Complex Substituents<br/><br/>4.4. Rings Made of Carbon: Cyclic Compounds<br/><br/>4.5. The Acid or Base Properties of Alkanes <br/><br/>4.6. Combustion Analysis and Empirical Formulas<br/><br/>4.7. Commercial and Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 5: Functional Groups<br/><br/>5.1. -Bonds. The C=C Unit and Alkenes<br/><br/>5.2. -Bonds. The CºC Unit and Alkynes<br/><br/>5.3. Hydrocarbons With Several -Bonds<br/><br/>5.4. Terpenes<br/><br/>5.5. Heteroatom Functional Groups<br/><br/>5.5.A. Alcohols and Thiols<br/><br/>5.5.B. Ethers and Dithioethers (Sulfides)<br/><br/>5.5.C. Amines<br/><br/>5.6. Functional Groups With Polarized -Bonds<br/><br/>5.6.A. The Carbonyl Functional Group, C=O<br/><br/>5.6.B. Ketones and Aldehydes<br/><br/>5.6.C. Carboxylic Acids, Carboxylic Anions and Resonance<br/><br/>5.6.D. Double and Triple Bonds to Nitrogen<br/><br/>5.7. Acid-Base Properties of Functional Groups<br/><br/>5.8. Physical Properties and Intermolecular Forces<br/><br/>5.8.A. Boiling Point<br/><br/>5.8.B. Solubility<br/><br/>5.8.C. Melting Point<br/><br/>5.9. Benzene: A Special Cyclic Hydrocarbon <br/><br/>5.10. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 6: Acids, Bases, and Nucleophiles<br/><br/>6.1. Acid-Base Equilibria<br/><br/>6.2. Carboxylic Acids and Sulfonic Acids <br/><br/>6.2.A. Carboxylic Acids<br/><br/>6.2.B Sulfonic Acids<br/><br/>6.3. Factors That Influence the Strength of a Carboxylic Acid<br/><br/>6.3.A. Stability of the Conjugate Base<br/><br/>6.3.B. Inductive Effects<br/><br/>6.3.C. Solvent Effects<br/><br/>6.4. Alcohols Are Amphoteric<br/><br/>6.5. Amines <br/><br/>6.6. Carbon Acids<br/><br/>6.6.A. Terminal Alkynes Are Weak Acids<br/><br/>6.6.B. -Hydrogen Atoms and Carbonyls<br/><br/>6.7. Organic Bases<br/><br/>6.7.A. Amines<br/><br/>6.7.B. Alcohols Are Bases<br/><br/>6.7.C. Ethers Are Bases<br/><br/>6.7.D. Carbonyl Compounds Are Bases<br/><br/>6.7.E. Alkenes and Alkynes Are Bases<br/><br/>6.8. Lewis Acids and Bases<br/><br/>6.9. Nucleophiles <br/><br/>6.10. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 7. Chemical Reactions, Bond Energy, and Kinetics<br/><br/> <br/><br/>7.1. A Chemical Reaction<br/><br/>7.2. Reactive Intermediates<br/><br/>7.2.A. Carbocations (Carbenium ions)<br/><br/>7.2.B. Carbanions<br/><br/>7.2.C. Radicals<br/><br/>7.3 Formal Charge<br/><br/>7.4. Free Energy: Enthalpy and Entropy<br/><br/>7.5. Bond Dissociation Enthalpy and Reactions<br/><br/>7.6. Transition States<br/><br/>7.7. Competing Reactions<br/><br/>7.8. Reversible Chemical Reactions<br/><br/>7.9. Reaction Curves and Intermediates<br/><br/>7.10. Mechanisms<br/><br/>7.11. Kinetics<br/><br/>7.11.A. Reaction Rate and First-Order Reactions<br/><br/>7.11.B. Second-Order Reactions<br/><br/>7.11.C. Half Life<br/><br/>7.11.D. No Reaction<br/><br/>7.12. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 8: Conformations<br/><br/>8.1. Rotation Around C—C Bonds<br/><br/>8.1.A. Staggered and Eclipsed Rotamers<br/><br/>8.1.B. Torsional Strain: Steric Hindrance and Energy Barriers<br/><br/>8.2. Longer Chain Alkanes<br/><br/>8.3. Influence of Heteroatoms on the Rotamer Population<br/><br/>8.3.A. Halogen Substituents<br/><br/>8.3.B. OH or NH Groups in Alcohols or Amines<br/><br/>8.4. Introducing -Bonds<br/><br/>8.5. Cyclic Alkanes<br/><br/>8.5.A. Strain and Steric Hindrance in Cyclic Alkanes<br/><br/>8.5.B. Conformations of C3–C5 Cycloalkanes<br/><br/>8.5.C. Conformationally Mobile Cyclohexane<br/><br/>8.6. Substituted Cyclohexanes. A1,3-Strain <br/><br/>8.7. Large Rings<br/><br/>8.8 Cyclic Alkenes<br/><br/>8.9. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 9: Stereoisomers: Chirality, Enantiomers, and Diastereomers<br/><br/>9.1. Stereogenic Carbons and Stereoisomers<br/><br/>9.2. Absolute Configuration [(R) and (S) Nomenclature] <br/><br/>9.3. Specific Rotation: A Physical Property<br/><br/>9.4. Circular Dichroism<br/><br/>9.5. Diastereomers <br/><br/>9.6. Alkenes<br/><br/>9.7. Cis and Trans Substituents Attached to Rings<br/><br/>9.8. Stereogenic Centers in Cyclic Molecules<br/><br/>9.9. Stereogenic Centers in Bicyclic Molecules<br/><br/>9.10. Optical Resolution<br/><br/>9.11. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 10: Acid–Base Reactions of -Bonds: Addition Reactions<br/><br/>10.1. Carbocation Stability<br/><br/>10.2. Alkenes React With Brønsted-Lowry Acids<br/><br/>10.3. Carbocation Rearrangements<br/><br/>10.4. Hydration Reactions of Alkenes<br/><br/>10.5. Alkenes React With Dihalogens<br/><br/>10.5.A Dihalogenation<br/><br/>10.5.B. Diastereoselectivity in the Dihalogenation Reaction of Alkenes<br/><br/>10.5.C. Reaction With Aqueous Solutions of Halogens (Hypohalous Acids)<br/><br/>10.6. Alkenes React With Borane<br/><br/>10.7. Alkenes React With Mercury(II) Compounds<br/><br/>10.8. Alkynes React as Bases<br/><br/>10.8.A. Reaction With Brønsted-Lowry Acids<br/><br/>10.8.B. Hydration of Alkynes<br/><br/>10.8.C. Dihalogenation of Alkynes<br/><br/>10.8.D. Hydroboration of Alkynes<br/><br/>10.8.E. Oxymercuration of Alkynes<br/><br/>10.9. Metathesis<br/><br/>10.10. Non-Ionic Reactions: Radical Reactions<br/><br/>10.11. Polymerization<br/><br/>10.12. Organization of Reaction Types<br/><br/>10.13. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 11: Substitution Reactions<br/><br/>11.1. Alkyl Halides, Sulfonate Esters, and the Electrophilic C—X Bond<br/><br/>11.2. The SN2 Reaction<br/><br/>11.2.A. Nucleophilic Approach to an Electrophilic Carbon<br/><br/>11.2.B. Reaction Rate and Energy Requirements<br/><br/>11.2.C. The Role of the Solvent<br/><br/>11.3. Functional Group Transformations Via the SN2 Reaction<br/><br/>11.4. The SN1 Reaction<br/><br/>11.5. Substitution Reactions of Alcohols<br/><br/>11.5.A. Alcohols React With Mineral Acids<br/><br/>11.5.B. Sulfur and Phosphorous Halide Reagents<br/><br/>11.5.C. Mitsunobu Reaction<br/><br/>11.6. Reactions of Ethers<br/><br/>11.6.A. Ethers React as Brønsted–Lowry Bases<br/><br/>11.6.B. Reactions of Epoxides <br/><br/>11.7. Free Radical Halogenation of Alkanes<br/><br/>11.8. C—H Substitution<br/><br/>11.9. Organization of Reaction Types<br/><br/>11.10. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 12: Elimination and p-Bond-Forming Reactions<br/><br/>12.1. Bimolecular Elimination <br/><br/>12.2. Stereochemical Consequences of the E2 Reaction <br/><br/>12.3. The E2 Reaction in Cyclic Molecules <br/><br/>12.4. Unimolecular Elimination: The E1 Reaction <br/><br/>12.5. Intramolecular Elimination <br/><br/>12.6. Elimination Reactions of Vinyl Halides: Formation of Alkynes <br/><br/>12.7. Substitution versus Elimination<br/><br/>12.8. Strength and Limitations of the Simplifying Assumptions<br/><br/>12.9. Organization of Reaction Types<br/><br/>12.10. Biological Relevance <br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>13: Spectroscopic Methods of Identification<br/><br/>13.1. Light and Energy<br/><br/>13.2. Mass Spectrometry<br/><br/>13.3. Infrared Spectroscopy<br/><br/>13.3.A. Absorbing Infrared Light and the Infrared Spectrophotometer<br/><br/>13.3.B. The Infrared Spectrum and Functional Group Absorptions<br/><br/>13.4. Nuclear Magnetic Resonance Spectroscopy<br/><br/>13.4.A. The Nuclear Magnetic Resonance Experiment<br/><br/>13.4.B. The Proton NMR Spectrum<br/><br/>13.5. Identifying Monofunctional Molecules <br/><br/>13.6. Carbon-13 NMR Spectroscopy: Counting the Carbons<br/><br/>13.7. Two-Dimensional (2D)-NMR<br/><br/>13.8. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 14: Organometallics<br/><br/>14.1. Organomagnesium Compounds<br/><br/>14.2. Grignard Reagents Are Bases and Nucleophiles<br/><br/>14.3. Organolithium Reagents<br/><br/>14.4. Organocuprates <br/><br/>14.5. Other Organometallic Compounds<br/><br/>14.6. Organization of Reaction Types<br/><br/>14.7. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 15: Oxidation<br/><br/>15.1. Defining an Oxidation <br/><br/>15.2. Oxidation of Alcohols <br/><br/>15.2.A. Chromium (VI) Oxidation of Alcohols <br/><br/>15.2.B. Swern Oxidation <br/><br/>15.3. Dihydroxylation of Alkenes<br/><br/>15.4. Epoxidation of Alkenes<br/><br/>15.5. Oxidative Cleavage<br/><br/>15.5. C—H Oxidation<br/><br/>15.6. Organization of Reaction Types<br/><br/>15.7. Biological Relevance <br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 16: Reactions of Aldehydes and Ketones<br/><br/>16.1. Aldehydes and Ketones<br/><br/>16.2. The Reaction of Ketones and Aldehydes With Strong Nucleophiles<br/><br/>16.3. Stereoselectivity<br/><br/>16.4. The Reaction of Ketones and Aldehydes With Weak Nucleophiles<br/><br/>16.4.A. Reaction With Water<br/><br/>16.4.B. Reaction With Alcohols<br/><br/>16.4.C. Reaction With Amines <br/><br/>16.5. Organization of Reaction Types<br/><br/>16.6. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 17: Reduction<br/><br/>17.1 Defining a Reduction <br/><br/>17.2. Hydride Reducing Agents <br/><br/>17.3. Hydride Reduction of Other Functional Groups <br/><br/>17.4. Catalytic Hydrogenation <br/><br/>17.4.A. Hydrogenation of Alkenes and Alkynes<br/><br/>17.4.B. Homogeneous Hydrogenation<br/><br/>17.4.C. Hydrogenation of Heteroatom Functional Groups <br/><br/>17.5. Dissolving Metal Reductions <br/><br/>17.6. Organization of Reaction Types<br/><br/>17.7. Biological Relevance <br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 18: Carboxylic Acid Derivatives and Acyl Substitution<br/><br/>18.1. Carboxylic Acids<br/><br/>18.2. Carboxylic Acid Derivatives: Structure and Nomenclature<br/><br/>18.3. Sulfonic Acids and Derivatives<br/><br/>18.4. Acyl Substitution and Hydrolysis of Carboxylic Acid Derivatives<br/><br/>18.5. Preparation of Acid Chlorides and Acid Anhydrides<br/><br/>18.6. Preparation of Esters<br/><br/>18.7. Baeyer-Villiger Oxidation<br/><br/>18.8. Preparation of Amides<br/><br/>18.9. Carboxylic Acid Derivatives React With Carbon Nucleophiles<br/><br/>18.10. Dicarboxylic Acid Derivatives<br/><br/>18.11. Nitrate Esters, Sulfate Esters, and Phosphate Esters<br/><br/>18.12. Nitriles Are Carboxylic Acid Derivatives<br/><br/>18.13. Fatty Acids and Lipids<br/><br/>18.14. Organization of Reaction Types<br/><br/>18.15. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 19: Aromatic Compounds and Benzene Derivatives<br/><br/>19.1. Benzene and Aromaticity<br/><br/>19.2. Functionalized Benzene Derivatives <br/><br/>19.2.A. Alkyl Substituents (Arenes)<br/><br/>19.2.B. Functional Groups on the Benzene Ring<br/><br/>19.3. Electrophilic Aromatic Substitution <br/><br/>19.3.A. Aromatic Substitution: Halogenation, Nitration, and Sulfonation<br/><br/>19.3.B. Friedel-Crafts Alkylation<br/><br/>19.3.C. Friedel-Crafts Acylation<br/><br/>19.4. Disubstituted Benzene Derivatives <br/><br/>19.4.A. Regioselectivity<br/><br/>19.4.B. Activating and Deactivating Substituents<br/><br/>19.4.C. Halogen Substituents<br/><br/>19.4.D. Aniline and Aniline Derivatives<br/><br/>19.5. Polysubstituted Benzene Derivatives<br/><br/>19.6. Aromatic Coupling Reactions<br/><br/>19.7. Reduction And Aromatic Compounds<br/><br/>19.8. Aromaticity in Monocyclic Molecules Other Than Benzene<br/><br/>19.9. Polynuclear Aromatic Hydrocarbons<br/><br/>19.9.A. Naphthalene, Anthracene, and Phenanthrene <br/><br/>19.9.B. Aromatic Substitution Reactions of Polycyclic Hydrocarbons<br/><br/>19.10. Nucleophilic Aromatic Substitution<br/><br/>19.11. Aromatic Amines and Diazonium Salts<br/><br/>19.12. Benzyne Intermediates <br/><br/>19.13. Synthesis of Aromatic Compounds<br/><br/>19.14. Spectroscopy of Aromatic Compounds<br/><br/>19.15. Organization of Reaction Types<br/><br/>19.16. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 20: Enolate Anions: Acyl Addition and Acyl Substitution<br/><br/>20.1. Aldehydes and Ketones Are Weak Acids<br/><br/>20.2. Non-nucleophilic Bases<br/><br/>20.3. Enolate Alkylation<br/><br/>20.4. The Aldol Condensation<br/><br/>20.5. The Zimmerman Model<br/><br/>20.6. The Intramolecular Aldol Condensation<br/><br/>20.7. Acid-Catalyzed Aldol Condensations<br/><br/>20.8. Ester Enolate Anions<br/><br/>20.8.A. Alkylation of Ester Enolate Anions<br/><br/>20.8.B. Acyl Substitution and Acyl Addition<br/><br/>20.8.C. Intramolecular Condensation: The Dieckmann Condensation<br/><br/>20.8.D. Malonic Ester Enolate Anions<br/><br/>20.9. Decarboxylation<br/><br/>20.10. The Knoevenagel Reaction, the Malonic Ester Synthesis, <br/><br/>and the Acetoacetic Acid Synthesis<br/><br/>20.11. Yid Reactions<br/><br/>20.12. Organization of Reaction Types<br/><br/>20.13. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 21: Difunctional Molecules: Dienes and Conjugated Carbonyl Compounds<br/><br/>21.1. Conjugation<br/><br/>21.2. Photochemistry of C=C and C=O<br/><br/>21.3. Detecting Conjugation With Ultraviolet Spectroscopy<br/><br/>21.4. Reactions of Conjugated -Bonds<br/><br/>21.5. Conjugate Addition<br/><br/>21.6. Reduction of Conjugated Systems<br/><br/>21.7. Organization of Reaction Types<br/><br/>21.8. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 22. Difunctional Molecules: Pericyclic Reactions<br/><br/>22.1. The Diels-Alder Reaction<br/><br/>22.2. Reactivity of Dienes and Alkenes<br/><br/>22.3. Selectivity in the Diels-Alder Reaction<br/><br/>22.4. Other Pericyclic Reactions: [3+2] [2+2]<br/><br/>22.5. Sigmatropic Rearrangements<br/><br/>22.6. Organization of Reaction Types<br/><br/>22.7. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 23: Heteroaromatic Compounds<br/><br/>23.1. Nitrogen, Oxygen and Sulfur in an Aromatic Ring<br/><br/>23.2. Substitution Reactions in Monocyclic Heterocyclic Aromatic Compounds<br/><br/>23.3. Heteroaromatic Compounds With More Than One Ring<br/><br/>23.4. Aromatic Substitution Reactions of Polycyclic Heterocycles<br/><br/>23.5. Reduced Heterocycles<br/><br/>23.6. Alkaloids<br/><br/>23.7. Biological Relevance<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 24: Multifunctional Compounds:<br/><br/>Amines, Amino Acids and Peptides<br/><br/>24.1. Reactions That Form Amines<br/><br/>24.2. Amino Acids<br/><br/>24.3. Reactions and Synthesis of -Amino Acids<br/><br/>24.4. Biological Relevance: Peptides <br/><br/>24.5. Biological Relevance: Proteins<br/><br/>24.6. Biological Relevance: Enzymes<br/><br/>24.7. Combinatorial Methods<br/><br/>24.8. Amino Acid Residue Identification in Proteins<br/><br/>24.9. End Group Analysis<br/><br/>24.10. Hormones<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK<br/><br/> <br/><br/>Chapter 25: Multifunctional Compounds: Carbohydrates<br/><br/>25.1. Polyhydroxy Carbonyl Compounds<br/><br/>25.1.A. Monosaccharides<br/><br/>25.1.B. Hemi-Acetals<br/><br/>25.1.C. The Anomeric Effect<br/><br/>25.1.D. Ketose Monosaccharides<br/><br/>25.1.E. Amino Sugars<br/><br/>25.2. Disaccharides, Trisaccharides, Oligosaccharides, and Polysaccharides<br/><br/>25.3. Reactions of Carbohydrates<br/><br/>25.4. Glycosides<br/><br/>25.5. Biological Relevance: Nucleosides and Nucleotides<br/><br/>25.6. Biological Relevance: Polynucleotides<br/><br/>Correlation of Homework with Concepts<br/><br/>ANSWERS TO IN-CHAPTER QUESTIONS<br/><br/>HOMEWORK |
| 520 ## - SUMMARY, ETC. |
|---|
| Summary, etc |
"This latest edition constitutes significant changes within this unique introductory technique to organic chemistry. The reactions and mechanisms it covers are the most fundamental concepts in organic chemistry that are applied to industry, biological chemistry, biochemistry, molecular biology, and pharmacy. Using an illustrated conceptual approach rather than presenting sets of principles and theories to memorize, it gives students a more concrete understanding of the material"-- |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name as entry element |
Chemistry, Organic |
| Form subdivision |
Textbooks. |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name as entry element |
Organic acids |
| Form subdivision |
Textbooks. |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name as entry element |
Chemical reactions |
| Form subdivision |
Textbooks. |
| 776 08 - ADDITIONAL PHYSICAL FORM ENTRY |
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| Display text |
Online version: |
| Main entry heading |
Smith, Michael, 1946 October 17- |
| Title |
Organic chemistry |
| Edition |
Third edition. |
| Place, publisher, and date of publication |
Boca Raton : Taylor and Francis, 2022 |
| International Standard Book Number |
9781003174929 |
| Record control number |
(DLC) 2021061055 |
| 906 ## - LOCAL DATA ELEMENT F, LDF (RLIN) |
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| a |
7 |
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cbc |
| c |
orignew |
| d |
1 |
| e |
ecip |
| f |
20 |
| g |
y-gencatlg |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
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| Source of classification or shelving scheme |
Dewey Decimal Classification |
| Koha item type |
General Books |
